The duo have come together to create a limited-edition shoe called Malangeli, which captures the 'twisted allure' of a classic screen villainess. The stylish footwear features a sculpted heel, which curls away from a wedge sole - giving off the effect of a tendril of smoke. Maleficent-inspired? Most definitely.
So what's it like to work with one of Hollywood's most in-demand women?
Says Louboutin: 'It is exciting to work with someone who has such a strong aesthetic and character.'
'Getting to know Angelina through a fun collaboration has been one of my GREATEST pleasures!!!'
Forever the philanthropists, profits from the new collection will benefit SOS Children's Villages to help orphaned and abandoned children.
Malangeli will be available to pre-order from 20 October 2014.More